Single-ion magnet behaviour of heptacoordinated Fe(II) complexes: on the importance of supramolecular organization.
نویسندگان
چکیده
Supramolecular organization of a metal complex may significantly contribute to the magnetization dynamics of mononuclear SMMs. This is illustrated for a heptacoordinated Fe(II) complex with rather moderate Ising-type anisotropy for which a slow magnetization relaxation with significant energy barrier was reached when this complex was properly organized in the crystal lattice. Incidentally, it is the first example of single-ion magnet behaviour of Fe(II) in a pentagonal bipyramid surrounding.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 17 شماره
صفحات -
تاریخ انتشار 2015